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Question: 
How do I sync users into DocuWare using Office 365 GCC High?
 
Answer: 
To sync users into DocuWare using Office 365 GCC High, there are two endpoints with different addresses that must be modified:

Navigate to %ProgramData%/DocuWare/ADSync, access the ADSyncConfiguration.xmland locate the AzureADProvider section (populates once AzureAD sync is first configured). Here, adept the IssueUrl and ResourceUrl values to use .us instead of .com.
Note: Please create a copy of this file for backup purposes before modifying the file.

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Once completed, save the file and proceed in syncing users from Office 365 GCC High.

KBA is applicable to Cloud and On-premise Organizations.